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Zinc Oxide microwires enhance LEDs

By using a piezoelectric material alongside a gallium nitride LED, the external efficiency can be amplified by a factor of more than four times.

Scientists have used zinc oxide microwires to significantly improve the efficiency at which GaN LEDs convert electricity to ultraviolet light.

The devices are believed to be the first LEDs whose performance has been enhanced by the creation of an electrical charge in a piezoelectric material using the piezo-phototronic effect.

By applying mechanical strain to the microwires, researchers at the Georgia Institute of Technology created a piezoelectric potential in the wires, and that potential was used to tune the charge transport and enhance carrier injection in the LEDs.

This control of an optoelectronic device with piezoelectric potential, known as piezo-phototronics, represents another example of how materials that have both piezoelectric and semiconducting properties can be controlled mechanically.

 



Studying LEDs

Zhong Lin Wang (right) and Ying Liu study LEDs whose performance has been enhanced through the piezo-phototronic effect. (Georgia Tech Photo: Gary Meek)

"By utilising this effect, we can enhance the external efficiency of these devices by a factor of more than four times, up to eight percent," said Zhong Lin Wang, a Regents professor in the Georgia Tech School of Materials Science and Engineering. "From a practical standpoint, this new effect could have many impacts for electro-optical processes - including improvements in the energy efficiency of lighting devices."

Because of the polarisation of ions in the crystals of piezoelectric materials such as ZnO, mechanically compressing or otherwise straining structures made from the materials creates a piezoelectric potential - an electrical charge. In the GaN LEDs, the researchers used the local piezoelectric potential to tune the charge transport at thep-n junction.

The effect was to increase the rate at which electrons and holes recombined to generate photons, enhancing the external efficiency of the device through improved light emission and higher injection current. "The effect of the piezo potential on the transport behaviour of charge carriers is significant due to its modification of the band structure at the junction," Wang explained.

The ZnO wires form the "n" component of a p-n junction, with the GaN thin film providing the "p" component. Free carriers were trapped at this interface region in a channel created by the piezoelectric charge formed by compressing the wires.

Traditional LED designs use structures such as quantum wells to trap electrons and holes, which must remain close together long enough to recombine. The longer that electrons and holes can be retained in proximity to one another, the higher the efficiency of the LED device will ultimately be.



The devices produced by the Georgia Tech team increased their emission intensity by a factor of 17 and boosted injection current by a factor of four when compressive strain of 0.093 percent was applied to the ZnO wire. That improved conversion efficiency by as much as a factor of 4.25.

LED improved



An LED whose performance has been enhanced through the piezo-phototronic effect is studied in the laboratory of Regents professor Zhong Lin Wang. (Georgia Tech Photo: Gary Meek)

The LEDs fabricated by the research team produced emissions at ultraviolet wavelengths (about 390 nm), but Wang believes the wavelengths can be extended into the visible light range for a variety of optoelectronic devices. "These devices are important for today's focus on green and renewable energy technology," he said.

In the experimental devices, a single ZnO micro/nanowire LED was fabricated by manipulating a wire on a trenched substrate. A magnesium-doped GaN film was grown epitaxially on a sapphire substrate by MOCVD, and was used to form a p-n junction with the ZnO wire.

A sapphire substrate was used as the cathode that was placed side-by-side with the GaN substrate with a well-controlled gap. The wire was placed across the gap in close contact with the GaN. Transparent polystyrene tape was used to cover the nanowire. A force was then applied to the tape by an alumina rod connected to a piezo nanopositioning stage, creating the strain in the wire.

The researchers then studied the change in light emission produced by varying the amount of strain in 20 different devices. Half of the devices showed enhanced efficiency, while the others - fabricated with the opposite orientation of the microwires --showed a decrease. This difference was due to the reversal in the sign of the piezopotential because of the switch of the microwire orientation from +c to -c.

High-efficiency ultraviolet emitters are needed for applications in chemical, biological, aerospace, military and medical technologies. Although the internal quantum efficiencies of these LEDs can be as high as 80 percent, the external efficiency for a conventional single p-n junction thin-film LED is currently only about three percent.

Beyond LEDs, Wang believes the approach pioneered in this study can be applied to other optical devices that are controlled by electrical fields.

"This opens up a new field of using the piezoelectric effect to tune optoelectronic devices," Wang said. "Improving the efficiency of LED lighting could ultimately be very important, bringing about significant energy savings because so much of the world's energy is used for lighting."

Further details of the research are reported in he paper “Enhancing Light Emission of ZnO Microwire-Based Diodes by Piezo-Phototronic Effect” by Yang et al inNano Letters.

DOI: 10.1021/nl202619d

This research was sponsored by the Defence Advanced Research Projects Agency and the U.S. Department of Energy.
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