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Perovskite Works As A Spintronic Semiconductor


US team makes spintronic green LED and spin valve from perovskite

When German mineralogist Gustav Rose stood on the slopes of Russia's Ural Mountains in 1839 and picked up a piece of a previously undiscovered mineral, which he named 'perovskite', he had never heard of transistors or diodes.

In 2017, University of Utah physicist Valy Vardeny called perovskite a "miracle material" for an emerging field of next-generation electronics, called spintronics, and he's standing by that assertion.

In a paper just published in Nature Communications, Vardeny, along with Jingying Wang, Dali Sun (now at North Carolina State University) and colleagues present two devices built using perovskite to demonstrate the material's potential in spintronic systems. Its properties, Vardeny says, bring the dream of a spintronic transistor one step closer to reality.

A conventional digital electronic system conveys a binary signal (think 1s and 0s) through pulses of electrons carried through a conductive wire. Spintronics can convey additional information via another characteristic of electrons, their spin direction (think up or down). Spin is related to magnetism. So spintronics uses magnetism to align electrons of a certain spin, or "inject" spin into a system.

Researchers are working toward the milestone of a spin transistor. Such a device requires a semiconductor material in which a magnetic field can easily manipulate the direction of electrons' spin--a property called spin-orbit coupling. It's not easy to build such a transistor, Wang says. "We keep searching for new materials to see if they're more suitable for this purpose."

Perovskites' value as a technological material has only became apparent in the past ten years. Because of that atomic structure, researchers have been developing perovskite into a material for making solar panels. By 2018 they'd achieved an efficiency of up to 23 percent of solar energy converted to electrical energy - a big step up from 3.8 percent in 2009.

In the meantime, Vardeny and his colleagues were exploring the possibilities of spintronics and the various materials that could prove effective in transmitting spin. Because of heavy lead atoms in perovskite, physicists predicted that the mineral may possess strong spin-orbit coupling. In a 2017 paper, Vardeny and physics assistant professor Sarah Li showed that a class of perovskites called organic-inorganic hybrid perovskites do indeed possess large spin-orbit coupling. Also, the lifetime of spin injected into the hybrid materials lasted a relatively long time. Both results suggested that this kind of hybrid perovskite held promise as a spintronics material.

Two spintronic devices

The next step, which Vardeny and Wang accomplished in their recent work, was to incorporate hybrid perovskite into spintronic devices. The first device is a spintronic LED. The semiconductor in a traditional LED contains electrons and holes. When electrons flow through the diode, they fill the holes and emit light.

Wang says that a spintronic LED works much the same way, but with a magnetic electrode, and with electron holes polarised to accommodate electrons of a certain spin. The LED lit up with circularly polarised electroluminescence, Wang says, showing that the magnetic electrode successfully transferred spin-polarised electrons into the material.The graph above shows the wavelengths of light emitted from the spintronic LED. The inset shows the green light from the device.

"It's not self-evident that if you put a semiconductor and a ferromagnet together you get a spin injection," Vardeny adds. "You have to prove it. And they proved it."

The second device is a spin valve. Similar devices already exist and are used in devices such as computer hard drives. In a spin valve, an external magnetic field flips the polarity of magnetic materials in the valve between an open, low-resistance state and a closed, high-resistance state.

Wang and Vardeny's spin valve does more. With hybrid perovskite as the device material, the researchers can inject spin into the device and then cause the spin to precess, or wobble, within the device using magnetic manipulation.

That's a big deal, the researchers say. "You can develop spintronics that are not only useful for recording information and data storage, but also calculation," Wang says. "That was an initial goal for the people who started the field of spintronics, and that's what we are still working on."

Taken together, these experiments show that perovskite works as a spintronic semiconductor. The ultimate goal of a spin-based transistor is still several steps away, but this study lays important groundwork for the path ahead.

"What we've done is to prove that what people thought was possible with perovskite actually happens," Vardeny says. "That's a big step."

'Spin-optoelectronic devices based on hybrid organic-inorganic trihalide perovskites' by Jingying Wang et al; Nature Communications volume 10, Article number: 129 (2019)

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