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Sun Can Create Solar Energy Materials

A new process could provide more precise control of the processing temperature needed to create CIS and CZTS solar cells
In a recent advance in solar energy, researchers have discovered a way to tap the sun not only as a source of power, but also to directly produce the solar energy materials that make this possible.

This breakthrough by chemical engineers at Oregon State University could soon reduce the cost of solar energy, speed production processes, use environmentally benign materials, and make the sun almost a “one-stop shop" that produces both the materials for solar devices and the eternal energy to power them.

The findings were published in RSC Advances, a journal of the Royal Society of Chemistry, in work supported by the National Science Foundation.

“This approach should work and is very environmentally conscious," comments Chih-Hung Chang, a professor of chemical engineering at Oregon State University, and lead author of the paper.

“Several aspects of this system should continue to reduce the cost of solar energy, and when widely used, our carbon footprint," Chang believes. “It could produce solar energy materials anywhere there’s an adequate solar resource, and in this chemical manufacturing process, there would be zero energy impact."

The work is based on the use of a “continuous flow" microreactor to produce nanoparticle inks that make solar cells by printing. Existing approaches based mostly on batch operations are more time-consuming and costly.

In this process, simulated sunlight is focused on the solar microreactor to rapidly heat it, while allowing precise control of temperature to aid the quality of the finished product. The light in these experiments was produced artificially, but the process could be done with direct sunlight, and at a fraction of the cost of current approaches.

“Our system can synthesise solar energy materials in minutes compared to other processes that might take thirty minutes to two hours," Chang notes. “This gain in operation speed can lower cost."

In these experiments, the solar materials were made with copper indium diselenide (CuInSe2 or CIS), but to lower material costs it might also be possible to use a compound such as copper zinc tin sulphide (Cu2ZnSnS4 or CZTS), Chang continues.



Solar reactor: A new technology invented at Oregon State University uses sunshine directly in the production of solar energy materials. (Graphic by Ki-Joong Kim)

And to make the process something that could work twenty-four hours a day, sunlight might initially be used to create molten salts that could later be used as an energy source for the manufacturing. This could provide more precise control of the processing temperature needed to create the solar energy materials.

State-of-the-art chalcogenide-based, thin film solar cells have already reached a fairly high solar energy conversion efficiency of about 20 percent in the laboratory, the researchers say, while costing less than silicon technology. Further improvements in efficiency should be possible, they add.

Another advantage of these thin-film approaches to solar energy is that the solar absorbing layers are, in fact, very thin; about 1 - 2 microns, instead of the 50 - 100 microns of more conventional silicon cells. This could ease the incorporation of solar energy into structures, by coating thin films onto windows, roof shingles or other possibilities.

The work is described in detail in the paper, "Two-step continuous-flow synthesis of CuInSe2 nanoparticles in a solar microreactor," by Peter B. Kreider et al in RSC Adv., 2014,4, 13827-13830

DOI: 10.1039/C4RA00467A

Additional support for this work was provided by the Oregon Nanoscience and Microtechnologies Institute, or ONAMI, and the Oregon Built Environment and Sustainable Technologies Centre, or Oregon BEST.

 





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