Perovskites: A Cheap Alternative For Faraday Rotators?
Researchers in Australia have found a way to manipulate laser light at a fraction of the cost of current technology
Researchers from from the University of Sydney in Australia have found a way to manipulate laser light at a fraction of the cost of current technology. The discovery, published in Advanced Science, could help drive down costs in industries as diverse as telecommunications, medical diagnostics and consumer optoelectronics.
The research team, led by Girish Lakhwani from the University of Sydney Nano Institute and School of Chemistry, has used inexpensive crystals, known as perovskites, to make Faraday rotators. These manipulate light in a range of devices across industry and science by altering a fundamental property of light - its polarisation. This gives scientists and engineers the ability to stabilise, block or steer light on demand.
Faraday rotators are used at the source of broadband and other communication technologies, blocking reflected light that would otherwise destabilise lasers and amplifiers. They are used in optical switches and fibre-optic sensors as well.
Lakhwani said: "The global optical switches market alone is worth more than $4.5 billion and is growing. The major competitive advantage perovskites have over current Faraday isolators is the low cost of material and ease of processing that would allow for scalability."
To date, the industry standard for Faraday rotators has been terbium-based garnets. Lakhwani and colleagues at the Australian Research Centre of Excellence in Exciton Science have used lead-halide perovskites, which could prove a less expensive alternative.
Lakhwani said: "Development and uptake of our technology could be aided by the excellent positioning of Australia within the Asia-Pacific region, which is growing rapidly due to increasing investments in its high-speed communication infrastructure."
"Interest in perovskites really started with solar cells," said Randy Sabatini, a postdoctoral researcher leading the project in the Lakhwani group.
"They are efficient and much less expensive than traditional silicon cells, which are made using a costly process known as the Czochralski or Cz method. Now, we're looking at another application, Faraday rotation, where the commercial standards are also made using the Cz method. Just like in solar cells, it seems like perovskites might be able to compete here as well."
In this paper, the team shows that the performance of perovskites can rival that of commercial standards for certain colours within the visible spectrum.
Collaboration is key
"As part of the ARC Centre of Excellence in Exciton Science (ACEx), we benefitted from the exchange of ideas through this high-calibre centre," Lakhwani said. Collaborators included the ACEx groups of Udo Bach at Monash University and Asaph Widmer-Cooper at Sydney, as well as the Anita Ho-Baillie group at UNSW. Ho-Baillie has since joined the University of Sydney as the inaugural John Hooke Chair of Nanoscience.
"We've been looking into Faraday rotation for quite some time," Lakhwani said. "It's very difficult to find solution-processed materials that rotate light polarisation effectively. Based on their structure, we were hoping that perovskites would be good, but they really surpassed our expectations."
Looking ahead, the search for other perovskite materials should be aided by modelling.
"For most materials, the classical theory used to predict Faraday rotation performs very poorly," said Stefano Bernardi, a postdoctoral researcher in the Widmer-Cooper group at the University of Sydney. "However, for perovskites the agreement is surprisingly good, so we hope that this will allow us to create even better crystals."
The team has also performed thermal simulations to understand how a real device would function. However, there is still work to be done to make commercial application a reality.
"We plan on continuing to improve the crystal transparency and growth reproducibility," said Chwenhaw Liao, from UNSW. "However, we're very happy with the initial progress and are optimistic for the future."
'Solution‐Processed Faraday Rotators Using Single Crystal Lead Halide Perovskites' by Randy Sabatini et al; Advanced Science 13 February 2020