Perovskite sandwich generates energy
KAUST researchers develop self-powered photodetector by coupling silicone-based polymers with an organometallic halide perovskite
Autonomy is a much-anticipated feature of next-generation microsystems, such as remote sensors, wearable electronic gadgets, implantable biosensors and nanorobots. Now, a team from KAUST (King Abdullah University of Science and Technology) led by Husam Alshareef, Jr-Hau He and Khaled Salama have developed small standalone devices by integrating maintenance-free power units that produce and use their own fuel instead of relying on an external power source.
Triboelectric nanogenerators (TENGs) capture mechanical energy from their surroundings, such as vibrations and random motion produced by humans, and convert it into electricity. In these tiny generators, frictional contact between materials of different polarity creates oppositely charged surfaces. Repeated friction causes electrons to hop between these surfaces, resulting in electric voltage.
"We exploited this triboelectric effect to harvest energy from simple movements, such as hand clapping, finger tapping and routine hand motion, to drive different types of sensors," says Alshareef.
The researchers have developed a self-powered photodetector by coupling the silicone-based polymer polydimethylsiloxane (PDMS) as a TENG with a material called organometallic halide perovskite. The lead-halide-based material features optoelectronic properties that are desirable in solar cells and LEDs.
To streamline their design and eliminate the need for a motion actuator, He's team fabricated the photodetector using two multilayered polymer-based sheets separated by a small gap. One sheet comprised the perovskite ultrathin film while the other contained a PDMS layer. The gap allowed the team to harness the triboelectric effect when the device was activated by finger tapping.
"The self-powered device showed excellent responsiveness to incident light, especially when exposed to light of low intensity", says Mark Leung, the lead author of the photodetector study. Because of its flexible and transparent polymer components, it also retained its performance after being bent 1,000 times and regardless of the orientation of the incident light.
Pushing the boundaries further, the researchers engineered a wearable self-powered bracelet that can store the converted mechanical energy by combining a carbon-fibre-embedded silicone nanogenerator with MXene microsupercapacitors (pictured above).
They incorporated nanogenerator and miniaturised electrochemical capacitors into a single monolithic device encased in silicone rubber. The leak-proof and stretchable shell provided a flexible and soft bracelet that fully conformed to the body. Fluctuations in the skin-silicone separation altered the charge balance between electrodes, causing the electrons to flow back and forth across the TENG and the microsupercapacitor to charge up.
In addition to exhibiting longer cycle life and short charging time, MXene microsupercapacitors can accumulate more energy in a given area than thin-film and micro-batteries, offering faster and more effective small-scale energy storage units for TENG-generated electricity. When active, the bracelet can use the stored energy to operate various electronic devices, such as watches and thermometers.
"Our ultimate goal is to develop a self-powered sensor platform for personalised health monitoring," says PhD student Qiu Jiang, the lead author of the self-charging band project. The team is now planning to introduce sensors into the system to detect biomarkers in human sweat.
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