Discovery May Aid Conversion of IR Light into Energy
LMU team show how resonance enhances energy exchange leading to increased generation of charge carriers - and better efficiency
Scientists from Ludwig-Maximilians-Universitaet (LMU) in Munich have found a new effect to do with the optical excitation of charge carriers in a solar semiconductor. They think it could help convert more infrared light, which is normally lost in solar devices, into usable energy.
Semiconductors are the most prominent materials to convert solar light into usable electric energy. The International Energy Agency (IEA) reported that half a million solar panels were installed every day around the world last year. However, semiconductor-based solar cells still suffer from relatively low energy conversion efficiencies.
The reason is that semiconductors efficiently convert the light from a quite small portion of the solar spectrum into electrical power. The spectral position of this window of light that can be efficiently converted is strongly related to the bandgap of the particular semiconductor. If the semiconductor is designed to absorb yellow light, longer-wavelength light will pass through the material without producing currents. Additionally, shorter-wavelength light (green, blue and UV light), that is more energetic than yellow light, will lose its additional amount of energy into heat. Obtaining higher energy conversion efficiencies from semiconductors is therefore still a big challenge.
To study these limitations, Aurora Manzi, a PhD student from the chair for photonics led by Jochen Feldmann, has measured the charge carrier density created by the absorption of multiple photons in perovskite nanocrystals, a novel and promising material for photovoltaic applications.
"Multiple photon absorption of long-wavelength light with an energy lower than the semiconductor absorption window is usually very inefficient", highlights Manzi, first author of the publication in Nature Communications and a student of the NIM graduate program. "I was therefore totally surprised to observe that for specific excitation wavelengths the efficiency of this process becomes drastically enhanced. At the beginning this did not make any sense to us!
Light and exciton 'overtones' in resonance
The team of LMU scientists realised that these resonances occur when multiples of two distinct fundamental frequencies become equal, namely that of the frequency of the primary light oscillation and that of the frequency of the band gap or more precisely of the exciton at the band-gap.
One could draw an analogy to resonance or overtone phenomena in acoustics, commonly used in music instruments. When intense red light impinges on nano-structured perovskite nanocrystals, a process similar to the generation of overtones in a guitar string takes place. The fundamental light wavelength generates higher order optical harmonics, that are overtones whose frequencies are integer multiples of the primary light oscillation. When such a 'light overtone' becomes resonant with an overtone of the excitonic band-gap, the energy exchange is enhanced leading to an increased generation of charge carriers or more precisely of multiple excitons at the band gap.
"The resonances observed are analogous to the physical phenomena taking place in two different strings of a guitar", continues Manzi. "If we associate the first string to the light excitation and the second string to the semiconductor excitonic band-gap, we know from acoustics that they will get into resonance if a certain harmonic of the first string will match another harmonic of the second string."
"The observation of this novel resonance phenomenon for optical excitations in excitonic semiconductors could pave the way for solar cells to more efficiently convert long-wavelength light into usable electric power", adds Feldmann, the leader of the research team. "This is an exciting new finding with a possible impact for future solar devices. Together with our colleagues from the Research Network "Solar Technologies Go Hybrid" (SolTech), we will now try to develop innovative applications by playing with such overtones."
'Resonantly enhanced multiple exciton generation through below-band-gap multi-photon absorption in perovskite nanocrystals' by Aurora Manzi et al; Nature Communications volume 9, Article number: 1518 (2018)
