US Team Makes New Perovskite Findings
University of Minnesota study opens up possibilities for new transparent materials that conduct electricity
A team at the University of Minnesota has made a discovery that blends the best of two sought-after qualities for touchscreens and smart windows - transparency and conductivity - in the wide-bandgap transparent perovskite barium stannate (BaSnO3).
The researchers, led by K. Andre Mkhoyan, are the first to observe metallic lines in a perovskite crystal. BaSnO3 has not been studied extensively for metallic properties. The finding was made using advanced transmission electron microscopy (TEM), a technique that can form images with magnifications of up to 10 million. The research is published in Science Advances.
"The conductive nature and preferential direction of these metallic line defects mean we can make a material that is transparent like glass and at the same time very nicely directionally conductive like a metal," said Mkhoyan, a TEM expert and the Ray D. and Mary T. Johnson/Mayon Plastics Chair in the Department of Chemical Engineering and Materials Science at the University of Minnesota's College of Science and Engineering. "This gives us the best of two worlds. We can make windows or new types of touch screens transparent and at the same time conductive. This is very exciting."
Line defects (the most common being dislocation) are a row of atoms that deviate from the normal order. Because dislocations have the same composition of elements as the host crystal, the changes in electronic band structure at the dislocation core, due to symmetry-reduction and strain, are often only slightly different than that of the host. The researchers needed to look outside the dislocations to find the metallic line defect, where defect composition and resulting atomic structure are vastly different.
"We easily spotted these line defects in the high-resolution scanning transmission electron microscopy images of these BaSnO3 thin films because of their unique atomic configuration and we only saw them in the plan view," said Hwanhui Yun, a graduate student in the Department of Chemical Engineering and Materials Science and a lead author of the study.
For this study, BaSnO3 films were grown by MBE in a lab at the University of Minnesota Twin Cities. Metallic line defects observed in these films propagate along film growth direction, which means researchers can potentially control how or where line defects appear - and potentially engineer them as needed in touchscreens, smart windows, and other future technologies that demand a combination of transparency and conductivity.
Perovskite crystals (ABX3) contain three elements in the unit cell. This gives it freedom for structural alterations such as composition and crystal symmetry, and the ability to host a variety of defects. Because of different coordination and bonding angles of the atoms in the line defect core, new electronic states are introduced and the electronic band structure is modified locally in such a dramatic way that it turns the line defect into metal.
'Metallic line defect in wide-bandgap transparent perovskite BaSnO3' by Hwanhui Yun et al; Science Advances 15 Jan 2021: Vol. 7, no. 3