Swiss Team Discovers Spontaneous CdSe Nanotubes
Automatically assembling tubes have between three and six walls that are perfectly uniform and just a few atoms thick
Researchers at the Ecole Polytechnique Federale de Lausanne (EPFL) in Switzerland have discovered semiconducting nanotubes made of CdSe that assemble automatically in solutions of metallic nanocrystals and certain ligands. The tubes have between three and six walls that are perfectly uniform and just a few atoms thick - making them the first such nanostructures of their kind.
What's more, the nanotubes possess photoluminescent properties: they can absorb light of a specific wavelength and then send out intense light waves of a different colour, much like quantum dots and quantum wells.
That means they can be used as fluorescent markers in medical research, for example, or as catalysts in photoreduction reactions, as evidenced by the removal of the colours of some organic dyes, based on the results of initial experiments. The researchers' findings have made the cover of ACS Central Science.
An accidental discovery
But the unique feature of these semiconducting nanotubes is how they are formed. "Our discovery happened almost by chance. We had set out to study the role that certain ligands play in making 2D semiconducting nanometric crystals," says Xiaopeng Huang, the study's lead author. But the research team found that some ligands caused molecules to spontaneously come together in precise cylindrical structures which until then had been impossible to create.
The researchers will now investigate the other physical and electrical properties of their nanotubes and look into methods for making nanotubes with just a single wall.
'Spontaneous Formation of CdSe Photoluminescent Nanotubes with Visible-light Photocatalytic Performance' by Xiaopeng Huang et al; ACS Central Science. 2019, 5, 6, 1017-1023