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Breakthrough In Blue Quantum Dot Technology

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Canadian team creates first blue perovskite LED with an external quantum efficiency higher than 10 percent

There are many things quantum dots could do, but the most obvious place they could change our lives is to make the colours on our TVs and screens more pristine. Research using the Canadian Light Source (CLS) at the University of Saskatchewan is helping to bring this technology closer to our living rooms.

Until now, blue-glowing quantum dots, which are crucial for creating a full range of colour, have proved particularly challenging for researchers to develop. However, University of Toronto (U of T) researcher Yitong Dong and collaborators have made a huge leap in blue quantum dot fluorescence, results they recently published in Nature Nanotechnology.

“The idea is that if you have a blue LED, you have everything. We can always down convert the light from blue to green and red,” says Dong. “Let's say you have green, then you cannot use this lower-energy light to make blue.”

The team's breakthrough has led to quantum dots that produce green light at an external quantum efficiency (EQE) of 22 percent and blue at 12.3 percent. The theoretical maximum efficiency is not far off at 25 percent, and this is the first blue perovskite LED reported as achieving an EQE higher than 10 percent.

Dong has been working in the field of quantum dots for two years in Edward Sargent's research group at the U of T. This increase in efficiency took time, an unusual production approach, and overcoming several scientific hurdles to achieve.

CLS techniques, particularly GIWAXS on the HXMA beamline, allowed the researchers to verify the structures achieved in their quantum dot films. This validated their results and helped clarify what the structural changes achieve in terms of LED performance.“The CLS was very helpful. GIWAXS is a fascinating technique,” says Dong.

The first challenge was uniformity, important to ensuring a clear blue colour and to prevent the LED from moving towards producing green light.

“We used a special synthetic approach to achieve a very uniform assembly, so every single particle has the same size and shape. The overall film is nearly perfect and maintains the blue emission conditions all the way through,” says Dong.

Next, the team needed to tackle the charge injection needed to excite the dots into luminescence. Since the crystals are not very stable, they need stabilising molecules to act as scaffolding and support them. These are typically long molecule chains, with up to 18 carbon-non-conductive molecules at the surface, making it hard to get the energy to produce light.

“We used a special surface structure to stabilize the quantum dot. Compared to the films made with long chain molecules capped quantum dots, our film has 100 times higher conductivity, sometimes even 1000 times higher.”

This performance is a key benchmark in bringing these nanocrystal LEDs to market. However, stability remains an issue and quantum dot LEDs suffer from short lifetimes. Dong is excited about the potential for the field and adds, “I like photons, these are interesting materials, and, well, these glowing crystals are just beautiful.”

'Bipolar-shell resurfacing for blue LEDs based on strongly confined perovskite quantum dots' by Yitong Dong et al; Nature Nanotechnology 15, no. 8 (2020): 668-674.

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