News Article
Next generation solar cell technology on the horizon
Quantum dots can be tightly packed and more efficient according to recent findings on PbS solar cells.
Researchers from the University of Toronto(U of T), King Abdullah University of Science & Technology (KAUST) and Pennsylvania State University (Penn State) claim to have created the most efficient colloidal quantum dot (CQD) solar cell ever.
Ted Sargent, Canada Research Chair in Nanotechnology at University of Toronto
Quantum dots are nanoscale semiconductors that capture light and convert it into electrical energy. Because of their small scale, the dots can be sprayed onto flexible surfaces, including plastics. This enables the production of solar cells that are less expensive than the existing silicon-based version.
“We figured out how to shrink the wrappers that encapsulate quantum dots down to the smallest imaginable size - a mere layer of atoms,” said Ted Sargent, one of the authors of the paper published in the latest issue of Nature Materials.
A crucial challenge for the field has been striking a balance between convenience and performance. The ideal design is one that tightly packs the quantum dots together. The greater the distance between quantum dots, the lower the efficiency.
Until now, say the researchers, quantum dots have been capped with organic molecules that separate the nanoparticles by a nanometre. On the nanoscale, that is a long distance for electrons to travel.
To solve this problem, the scientists used inorganic ligands, sub-nanometre sized atoms that bind to the surfaces of the quantum dots and take up less space. The combination of close packing and charge trap elimination enabled electrons to move rapidly and smoothly through the solar cells, thus providing record efficiency.
“We wrapped a single layer of atoms around each particle. This allowed us to pack well-passivated quantum dots into a dense solid,” explained Jiang Tang, the first author of the paper who conducted the research whilst a post-doctoral fellow in the Edward S. Rogers Department of Electrical and Computer Engineering at U of T.
“Our team at Penn State proved that we could remove charge traps - locations where electrons get stuck - while still packing the quantum dots closely together,” said John Asbury of Penn State, a co-author of the work.
“At KAUST, we used visualisation methods with sub-nanometer resolution and accuracy to investigate the structure and composition of the passivated quantum dots,” stated another co-author Aram Amassian of KAUST in Saudi Arabia. “We proved that the inorganic passivants were tightly correlated with the location of the quantum dots and that it was the chemical passivation, rather than nanocrystal ordering, that led to the remarkable colloidal quantum dot solar cell performance.”
“It is very impressive that the team was able to make solar cells with power conversion efficiency up to 6% from quantum dots,” stated Michael McGehee of Stanford University, an expert in solution-processed organic solar cells.”
There is a lot of surface area in these films that could have dangling bonds which would hinder the performance of solar cells by creating traps states. The team says its quantum dots have the highest electrical currents and the highest overall power conversion efficiency ever seen in CQD solar cells. The performance results were certified by an external laboratory, Newport, which is accredited by the U.S. National Renewable Energy Laboratory.
“This work proves the power of inorganic ligands in building practical devices,” said Dmitri Talapin of The University of Chicago, a pioneer in inorganic ligands and materials chemistry.
“This new surface chemistry provides the path toward both efficient and stable quantum dot solar cells. It should also impact other electronic and optoelectronic devices that utilise colloidal nanocrystals. Advantages of the all-inorganic approach include vastly improved electronic transport and a path to long-term stability.”
As a result of the potential of this research discovery, a technology licensing agreement has been signed by U of T and KAUST, brokered by MaRS Innovations (MI), which will enable the global commercialisation of this new technology.
“The world and the marketplace need solar innovations that break the existing compromise between performance and cost. Through the partnership between U of T, MI and KAUST, we are poised to translate exciting research into tangible innovations that can be commercialised,” concluded Sargent.
