The lasers are nanometre-sized semiconductor particles called colloidal quantum dots (CQDs) with an inner core of cadmium and selenium alloy and a coating of zinc, cadmium, and sulphur alloy. Adjusting the size of the pyramid-shaped QDs changes the laser light colour

Engineers at Brown University and QD Vision have created nanoscale single crystals that can produce  red, green, or blue laser light needed in digital displays.

The size determines colour, but all the pyramid-shaped quantum dots are made the same way of the same elements. In experiments, light amplification required much less power than previous attempts at the technology. The team’s prototypes are claimed to be the first lasers of their kind.

Red, green, and blue lasers have become small and cheap enough to find their way into products ranging from BluRay DVD players to fancy pens. But each colour is made with different semiconductor materials and by elaborate crystal growth processes.

Now a new innovative technology demonstrates all three of those colours coming from one material. That could open the door to making products, such as high-performance digital displays, that employ a variety of laser colours all at once.



VCSEL colloidal quantum dots, also known as nanocrystals, can produce lasers of many colours. Cuong Dang manipulates a green beam that pumps the nanocrystals with energy, in this case producing red laser light. (Credit: Mike Cohea/Brown University)

“Today in order to create a laser display with arbitrary colours, from white to shades of pink or teal, you’d need these three separate material systems to come together in the form of three distinct lasers that in no way shape or form would have anything in common,” notes Arto Nurmikko, professor of engineering at Brown University and senior author of a paper describing the innovation. “Now enter a class of materials called semiconductor quantum dots.”

The materials in prototype lasers described in the paper are nanometre-sized semiconductor particles called colloidal quantum dots (CQDs) or nanocrystals with an inner core of cadmium and selenium alloy and a coating of zinc, cadmium, and sulphur alloy and a proprietary organic molecular glue.

Chemists at QD Vision synthesised the nanocrystals using a wet chemistry process that allows them to precisely vary the nanocrystal size by varying the production time. Size is all that needs to change to produce different laser light colours: 4.2 nm cores produce red light, 3.2 nm ones emit green light and 2.5 nm ones shine blue. Different sizes would produce other colours along the spectrum.

The cladding and the nanocrystal structure are critical advances beyond previous attempts to make lasers with colloidal quantum dots, said lead author Cuong Dang, a senior research associate and nanophotonics laboratory manager in Nurmikko’s group at Brown. Because of their improved quantum mechanical and electrical performance, he said, the coated pyramids require 10 times less pulsed energy or 1,000 times less power to produce laser light than previous attempts at the technology.

Quantum nail polish

When chemists at QDVision brew a batch of colloidal quantum dots for Brown-designed specifications, Dang and Nurmikko get a vial of a viscous liquid that Nurmikko said somewhat resembles nail polish.

To make a laser, Dang coats a square of glass, or a variety of other shapes, with the liquid. When the liquid evaporates, what’s left on the glass are several densely packed solid, highly ordered layers of the nanocrystals. By sandwiching that glass between two specially prepared mirrors, Dang creates one of a VCSEL. The Brown-led team says it was the first to make a working VCSEL with colloidal quantum dots.

The nanocrystals’ outer coating alloy of zinc, cadmium, sulphur and that molecular glue is important because it reduces an excited electronic state requirement for lasing and protects the nanocrystals from a kind of crosstalk that makes it hard to produce laser light, Nurmikko says. Every batch of colloidal quantum dots has a few defective ones, but normally just a few are enough to interfere with light amplification.

Faced with a high excited electronic state requirement and destructive crosstalk in a densely packed layer, previous groups have needed to pump their dots with a lot of power to push them past a higher threshold for producing light amplification, a core element of any laser.

Pumping them intensely, however, gives rise to another problem: an excess of excited electronic states called excitons. When there are too many of these excitons among the quantum dots, energy that could be producing light is instead more likely to be lost as heat, mostly through a phenomenon known as the Auger process.

The nanocrystals’ structure and outer cladding reduces destructive crosstalk and lowers the energy needed to get the quantum dots to shine. That reduces the energy required to pump the quantum dot laser and significantly reduces the likelihood of exceeding the level of excitons at which the Auger process drains energy away. In addition, a benefit of the new approach’s structure is that the dots can act more quickly, releasing light before Auger process can get started, even in the rare cases when it still does start.

“We have managed to show that it’s possible to create not only light, but laser light,” Nurmikko says. “In principle, we now have some benefits: using the same chemistry for all colours, producing lasers in a very inexpensive way, relatively speaking, and the ability to apply them to all kinds of surfaces regardless of shape. That makes possible all kinds of device configurations for the future.”

 

The US. Department of Energy, the Air Force Office for Scientific Research, and the National Science Foundation supported the research. Dang is a Vietnam Education Foundation (VEF) Scholar.

Further details of this work has been published in the paper,"Red, green and blue lasing enabled by single-exciton gain in colloidal quantum dot films", by Dang et al, Nature Nanotechnology, 7, 335–339 (2012).     DOI:10.1038/nnano.2012.61