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Optimising InGaAs metamorphic buffer for laser diodes

Using Laytec's EpiCurve TT, NTT has improved it's thin InGaAs buffer layer to exhibit lower thermal resistance
Temperature characteristics of laser diodes (LDs) on a GaAs substrate depend on the quality and the thermal resistance of the InGaAs metamorphic buffer layer.

At the Electronic Materials Symposium in Japan in July 2013, NTT Photonics Laboratories (NTT) presented a new method for optimisation of the metamorphic buffer layer for freestanding quasi-InGaAs substrates.

Ryo Nakao from NTT used LayTec‘s in-situ metrology system EpiCurve TT to improve layer thickness and indium content in order to fabricate a thin InGaAs metamorphic buffer with low thermal resistance.

The in-situ tool helps understand the MOCVD growth conditions and shows the changes in wafer curvature caused by residual strain during MOCVD growth.



Fig. 1: In-situ curvature data of InGaAs buffer and quasi-InGaAs substrate on GaAs substrate

Fig. 1 shows in-situ curvature data for a 1250 nm metamorphic InGaAs buffer layer and a quasi-InGaAs substrate layer. The growth can be separated into 3 parts: I - Coherent (pseudomorphic) growth of the buffer, II - Growth with relaxation, III - Free-standing (unstrained) growth.

During relaxation, the in-plane lattice constant of the In0.12Ga0.88As layer increases. After the buffer has reached 1250 nm, its lattice constant exactly matches the lattice constant of In0.1Ga0.9As. As a result, the wafer curvature does not change during the subsequent growth of In0.1Ga0.9As layer.

The authors call this final growth phase “free-standing” because the In0.1Ga0.9As layer grows with its natural lattice constant and creates a quasi-substrate similar to an In0.1Ga0.9As wafer for the later device growth.

With a buffer thickness of 1000 nm, further experiments with the same indium content and different buffer thicknesses showed that if the relaxation is not sufficient , the quasi- In0.1Ga0.9As substrate growth is compressively strained.

However, over-relaxation (1600 nm) results in a tensile strain.

The researchers plotted these changes to obtain a map of the correlation between thickness and curvature. For a free-standing quasi-InGaAs substrate, they choose a buffer thickness with no further variation in curvature over time during In0.1Ga0.9As growth.

This work shows that in-situ curvature measurements are a decisive part of an innovative technology that is developed to improve characteristics of LDs.

Ryo Nakao et al describe further details of this work in the EMS-32 proceedings (2013).





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