News Article
III-V multilayer tiny solar cells enable super efficient power generation
Researchers at the University of Illinois at Urbana-Champaign have used a printing process to assemble tiny cells into multilayer stacks for extraordinary levels of photovoltaic conversion efficiency
As an energy source, the sun has always been a dependable provider. Although it freely shines on everyone, the ability to capture and convert the sun's abundant energy is anything but free.
However, new technologies aimed at achieving "full spectrum" operation in utility-scale photovoltaics may soon make solar energy a viable option.
"A few simple ideas in materials science and device assembly allow us to bypass many of the limitations of traditional photovoltaic technologies," explains John Rogers, whose research group is developing these concepts. As a result of these new efficiencies, external industry experts project solar energy electricity generation costs that can reach, without subsidies, levels that are lower than coal, natural gas, and nuclear.
A professor of materials science and engineering at the University of Illinois at Urbana-Champaign, Rogers is a pioneer in semiconductor devices and manufacturing techniques. A printing approach, developed by Rogers and colleagues at Illinois, allows manipulation of ultrathin, small semiconductor elements that can be stacked on top of one another to yield an unusual type of solar cell capable of operating across the entire solar spectrum at exceptionally high efficiency.
"The strategy involves high-speed, printing-based manipulation of thin, microscale solar cells and new interface materials to bond them into multilayer stacks," Rogers says. "Quadruple-junction, four-terminal solar cells that we can build in this way have individually measured efficiencies of 43.9 percent."
This shows printing-based assembly process yields arrays of stacked multi-junction cells in a fully automated step-and-repeat mode with high yields and accurate overlay registration (Credit : Xing Sheng, University of Illinois)
"This is a high-throughput, parallel assembly process that allows for simultaneous formation of arrays of stacked multi-junction cells in a fully automated step-and-repeat mode with high yields - greater than 95 percent - and accurate overlay registration. A newly developed interfacial material for these stacks enables ideal optical, electrical, and thermal properties, " states Xing Sheng, a postdoctoral fellow with Rogers' research group and first author of a paper published in the journal Nature Materials.
The project involved a collaborative team of researchers at the University of Illinois and the photovoltaic companies Semprius and Solar Junction. According to the group's paper, the module's top cell consists of a three-junction (3J) microcell with its own anti-reflective coating to ensure efficient transmission of light to the uppermost layers. The bottom cell uses a diffused-junction germanium architecture.
The 3J microcell is composed of InGaP/GaAs/InGaAsNSb layers.
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The top cell in the stacked 3-junction/germanium assembly captures wavelengths between 300 nm and 1300 nm; wavelengths from 1300 nm to 1700 nm pass through to the bottom cell (Credit : Xing Sheng, University of Illinois)
In a stacked 3J/Ge assembly, the top 3J cell captures light with wavelengths between 300 nm and 1300 nm. Wavelengths from 1300 nm to 1700 nm pass through to the bottom germanium cell with minimal interface reflections, due to the use of a thin layer of a unique type of chalcogenide glass.
"We integrated these microscale, multijunction cells into Semprius' dual-stage optics - consisting of a molded primary lens and a secondary, miniature ball lens - to tightly focus incident sunlight by more than one thousand times," Rogers explains. "Advanced packaging techniques and electrical matching networks yield fully integrated modules with efficiencies of 36.5 percent evaluated under practical conditions - significantly better than any other available technology."
Dual-stage optics, consisting of a molded 2 X 2 cm2 primary lens and a secondary, 2 mm ball lens (inset) focus incident sunlight by more than one thousand times (Credit : Xing Sheng, University of Illinois)
"This is very nice work. The results are impressive, and the schemes appear to provide a route to ultra-high efficiency photovoltaics, with strong potential for utility-scale power generation," states Ali Javey, a professor of electrical engineering and computer sciences at the University of California, Berkeley. Javey, who is a program leader for electronic materials at the Lawrence Berkeley National Laboratory and a co-director of the Bay Area Photovoltaics Consortium, was not involved with this research.
This work has been published in the paper, "Printing-based assembly of quadruple-junction four-terminal microscale solar cells and their use in high-efficiency modules," by Xing Sheng et al in Nature Materials (2014). doi:10.1038/nmat3946
However, new technologies aimed at achieving "full spectrum" operation in utility-scale photovoltaics may soon make solar energy a viable option.
"A few simple ideas in materials science and device assembly allow us to bypass many of the limitations of traditional photovoltaic technologies," explains John Rogers, whose research group is developing these concepts. As a result of these new efficiencies, external industry experts project solar energy electricity generation costs that can reach, without subsidies, levels that are lower than coal, natural gas, and nuclear.
A professor of materials science and engineering at the University of Illinois at Urbana-Champaign, Rogers is a pioneer in semiconductor devices and manufacturing techniques. A printing approach, developed by Rogers and colleagues at Illinois, allows manipulation of ultrathin, small semiconductor elements that can be stacked on top of one another to yield an unusual type of solar cell capable of operating across the entire solar spectrum at exceptionally high efficiency.
"The strategy involves high-speed, printing-based manipulation of thin, microscale solar cells and new interface materials to bond them into multilayer stacks," Rogers says. "Quadruple-junction, four-terminal solar cells that we can build in this way have individually measured efficiencies of 43.9 percent."
This shows printing-based assembly process yields arrays of stacked multi-junction cells in a fully automated step-and-repeat mode with high yields and accurate overlay registration (Credit : Xing Sheng, University of Illinois)
"This is a high-throughput, parallel assembly process that allows for simultaneous formation of arrays of stacked multi-junction cells in a fully automated step-and-repeat mode with high yields - greater than 95 percent - and accurate overlay registration. A newly developed interfacial material for these stacks enables ideal optical, electrical, and thermal properties, " states Xing Sheng, a postdoctoral fellow with Rogers' research group and first author of a paper published in the journal Nature Materials.
The project involved a collaborative team of researchers at the University of Illinois and the photovoltaic companies Semprius and Solar Junction. According to the group's paper, the module's top cell consists of a three-junction (3J) microcell with its own anti-reflective coating to ensure efficient transmission of light to the uppermost layers. The bottom cell uses a diffused-junction germanium architecture.
The 3J microcell is composed of InGaP/GaAs/InGaAsNSb layers.
The top cell in the stacked 3-junction/germanium assembly captures wavelengths between 300 nm and 1300 nm; wavelengths from 1300 nm to 1700 nm pass through to the bottom cell (Credit : Xing Sheng, University of Illinois)
In a stacked 3J/Ge assembly, the top 3J cell captures light with wavelengths between 300 nm and 1300 nm. Wavelengths from 1300 nm to 1700 nm pass through to the bottom germanium cell with minimal interface reflections, due to the use of a thin layer of a unique type of chalcogenide glass.
"We integrated these microscale, multijunction cells into Semprius' dual-stage optics - consisting of a molded primary lens and a secondary, miniature ball lens - to tightly focus incident sunlight by more than one thousand times," Rogers explains. "Advanced packaging techniques and electrical matching networks yield fully integrated modules with efficiencies of 36.5 percent evaluated under practical conditions - significantly better than any other available technology."
Dual-stage optics, consisting of a molded 2 X 2 cm2 primary lens and a secondary, 2 mm ball lens (inset) focus incident sunlight by more than one thousand times (Credit : Xing Sheng, University of Illinois)
"This is very nice work. The results are impressive, and the schemes appear to provide a route to ultra-high efficiency photovoltaics, with strong potential for utility-scale power generation," states Ali Javey, a professor of electrical engineering and computer sciences at the University of California, Berkeley. Javey, who is a program leader for electronic materials at the Lawrence Berkeley National Laboratory and a co-director of the Bay Area Photovoltaics Consortium, was not involved with this research.
This work has been published in the paper, "Printing-based assembly of quadruple-junction four-terminal microscale solar cells and their use in high-efficiency modules," by Xing Sheng et al in Nature Materials (2014). doi:10.1038/nmat3946
